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moncler outlet CuGeO3的电子&am

 
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Cholerny Spammer



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PostPosted: Thu 18:03, 31 Mar 2011    Post subject: moncler outlet CuGeO3的电子&am

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CuGeO3的电子顺磁共振研究
仅成功地解释了自由离子谱,而且也解释了d—d晶场跃迁,电子顺磁共振和光谱的高压、温度效应.对于Cu离子有:a1—0.790,[link widoczny dla zalogowanych],a20.523,f1—5.9503,1.1897代(9)至(12)式得=940cm_。,(r2)=3.1la5,[link widoczny dla zalogowanych],()一44.80a此处a,[link widoczny dla zalogowanych]。是波尔半径.将上述各值代矩阵公式(6),取o}_配体有效电荷g=一1.2e_1求得CuGeO。的部分能级为:(4=12790cm~,△=12910cm,[link widoczny dla zalogowanych],(4=12940cm)和波函数混合系数(口=0.81,口一0.99,.9—0.14)则基态波函数为:一0.81(0:991一>十0.1413Z一r>)l10河南师范大学学报(自蒜科学簸)1997芷由(7)式求得g因子为:(一2.15,g;2.06,和g。一2.3Cool与实验测定各g值(一2.15,g=2.06,g=2.26)基本符合一致-
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